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winter-hater club member
 
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distillation at room temperature....

could this be the way to make ethanol a commercially and energy viable fuel?

Hi-tech 'wonder material' graphene has an unexpected use - it can distill vodka at room temperature | Mail Online

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Old 05-28-2012, 07:21 PM
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Whoa... Thats cool... And freaky...
Old 05-28-2012, 07:26 PM
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yep, pretty cool. i suspect it is due to water being a relatively small molecule and polar.
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Old 05-28-2012, 07:38 PM
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I'd suspect that its due more to polarity than size. If it was just size based it would let smaller molecules through, like oxygen and hydrogen on their own.... But it blocks those.....
Old 05-28-2012, 07:44 PM
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ah.... right.

i wonder if the material has some electrical properties, other than conduction. as in, does the water pass due to an inducted current, or something like that.

edit: isn't oxygen polar, also?
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Old 05-28-2012, 07:54 PM
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As a gas oxygen forms 02 due to its polarity, and making it less reactive....
Old 05-28-2012, 07:56 PM
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gotcha. its been over a decade since i had chemistry.
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Old 05-28-2012, 08:09 PM
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Don't worry, we get much more complex than this and I'll be breaking out the text books. I may have had 2 years of college chemistry, but thats still some confusing stuff.....
Old 05-28-2012, 09:10 PM
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Quote:
Originally Posted by porsche4life View Post
As a gas oxygen forms 02 due to its polarity, and making it less reactive....
Can you clarify? Oxygen is non-polar.
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Old 05-28-2012, 11:20 PM
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Polar is the wrong term. Oxygen is charged, it forms O2 in an effort to stabilize itself.
Old 05-29-2012, 04:21 AM
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I read about this a while back, they were talking about the conductivity of it, and having cell phones you could roll up like a pencil and put in your pocket.
Old 05-29-2012, 09:51 AM
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In their example, they removed water from vodka.
The article states that "it blocks all liquids and gases except water."

So, this could not be used for distillation from mash, as the water would pass through the graphene and leave behind the alcohol, fusil oils, organic material, etc.
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Old 05-29-2012, 10:56 AM
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I suspect you could take mash, run it through filters to remove solids, then through the membrane, but I suspect the resulting fluid might be , ah, er less than 'optimum'.

Best
Les
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Old 05-29-2012, 12:29 PM
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Quote:
Originally Posted by oldE View Post
I suspect you could take mash, run it through filters to remove solids, then through the membrane, but I suspect the resulting fluid might be , ah, er less than 'optimum'.

Best
Les
yep, run it through a filter. the fusel oils (long chain alcohols) are flammable. doubt that a mash is distilled prior to filtering.

less than desirable for a beverage, for sure. for fuel, perfect.
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Old 05-29-2012, 02:03 PM
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LOL we have a low temperature distillation unit where I work that processes 3/4 million gallons a day.
This particular distillation tower operates at lower than atmospheric pressure which reduces the boiling points of the liquid inside, and the energy required to seperate it by boiling point.

This is what the vac distillation tower looks like. You don't want to know what something like that costs new:


Last edited by sammyg2; 05-29-2012 at 02:07 PM..
Old 05-29-2012, 02:04 PM
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imagine if you used that membrane and a vacuum. i bet it could be done with zero heating.

that is some cool equipment, sammy.

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Old 05-29-2012, 02:47 PM
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