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White paint reflects nearly everything, black paint absorbs nearly everything. Absorbing nearly everything turns into heat. I say nearly everything because I doubt many cars are pure white or pure black. Matching paint can be a little sloppily with blending, which tricks the eye into not noticing the color difference. A friend of mine who used to own a high-end bodyshop said black was the hardest to match.
PDR is so good when possible and done by a good technician.
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