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Save yourself a lot of headache so you can concentrate on the training for the 100 mile ride. Aerorims are amazingly fast but that's the drawback from lack of speed. They are a deficit due to weight only because there's a bit more mass but if you go ultra light carbon wheels, weight is cut down a bit. If your plan is to go out and do this 100 mile ride within reasonable amount of time, then carbon deep dish wheel maybe a consideration if not, those Mavic rims laced to the Campy hubs will more then enough to enjoy that ride. They are light and their box shape is durable.