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Only way to make the D drive bootable is to make it the C drive. So, before you copy, make a bootable floppy with FDISK and Format on it. Disconnect your C:, make D: the primary drive and boot from the floppy. FDISK, create a primary partition on the new C:. Then Format C: /s. When the format is done, shut down, put the drives back the way they were and do your xcopy. Then disconnect C again and verify what you did works.
Good Luck.
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